writer：Qi Zhang, Milin Fu, Chengjian Wang, Jianli Wang,Shiping Zhu
keywords：Poly(ionic liquid) Nanoparticles,RAFT/MADIX PISA
source：期刊
specific source：Polymer Chemistry
Issue time：2017年

We report herein a facile method for hierarchical regulation of the morphology of poly(ionic liquid) (PIL) nanoparticles through RAFT/MADIX aqueous polymerization-induced self-assembly of 3-n-dodecyl-1-vinylimidazolium bromide, by using PEG-xanthate as the macro-CTA. Rigid straight rods were formed over a broad composition range even at low solids, due to the high

incompatibility between the charged PIL block and the neutral PEG block.