作者：Jian Li, Hongyao Niu, Yingfeng Yu, Yulei Gao, Qiang Wu, Fenfen Wang,* and Pingchuan Sun*
关键字：PDMS elastomer, self-healing, synergetic dynamic bonds, oil/water separation, hot-melt adhesive
论文来源：期刊
具体来源：ACS Appl. Polym. Mater. 2021, 3, 3373?3382
发表时间：2021年
Hydrophobic elastomers are required for use in industry and daily life because of their versatile properties. Developing a hydrophobic elastomer with selfhealing abilities and excellent mechanical performance has been very challenging because of the mutually exclusive nature of these properties. Herein, supramolecular polydimethylsiloxane (PDMS) elastomers with excellent self-healing and mechanical properties were designed through the synergetic combination of multistrength H-bonds and disulfide bonds. The hierarchical H-bonds formed with urethane, urea, and 2-ureido-4[1H]-pyrimidinone (UPy) moieties in the backbone of the supramolecular polymer endow the resultant polymers with effective reversible cross-linking, whereas during stretching, the dynamic dissociation and reassociation of H-bonds enable polymers with high extensibility and enhanced toughness and recoverability. In addition, disulfide bond exchange under heat enables polymer network rearrangement, thus imbuing the supramolecular elastomer with excellent self-healing ability. Based on the extraordinary properties of hydrophobic supramolecular PDMS elastomers, some smart materials can be prepared, such as oil/water separation foams and hydrophobic hot-melt adhesives. Therefore, this concept of synergetic dynamic bonds will point out a direction
for the development of sustainable, green, and functional materials of the next generation.