writer：Wang, XL; Gao, Y; Mao, KM; Xue, G; Chen, TH; Zhu, JJ; Li, BH; Sun, PC; Jin, QH; Ding, DT; Shi, AC
keywords：rheology, exfoliation, orientation-disorientation, liquid rubber, organo-clay, nanocomposites
source：期刊
specific source：Macromolecules2006, 39, 6653-6660
Issue time：2006年
The rheological properties of liquid polybutadiene rubber/organo-clay nanocomposite gels were investigated by rheological experiments, focusing on the effects of clay exfoliation and orientation-disorientation as well as polymer-clay interaction and temperature. Both irreversible and reversible viscosity transitions were observed in the temperature range from 26 to 136 °C in steady shear experiments on as-prepared and exfoliated samples. These transitions depend strongly on the end groups, molecular weight of the liquid rubber, and the shear field. The irreversible transition is attributed to the exfoliation of the clay, and the reversible transition can be understood as a shear-induced orientation-disorientation transition of the clay sheets. Polymer-clay interaction is confirmed to be a key controlling factor of the orientation-disorientation transition, whereas the shear field plays a critical role to induce such a transition. To our knowledge, this is the first rheological observation of the in-situ exfoliation process and the shear-induced orientation-disorientation transition of layered silicate in polymer/organo-clay nanocomposites. A tentative model was suggested on the basis of the clay exfoliation and orientationdisorientation transition, and the model is used to explain the observed unique rheological behavior.