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87. (Green Chem.) Upcycling of Post-consumer Polyolefin Plastics to Covalent Adaptable Networks via In-situ Continuous Extrusion Cross-linking
作者:Sheng Wang, Songqi Ma,* Jianfan Qiu, Anping Tian, Qiong Li, Xiwei Xu, Binbo Wang, Na
关键字:Plastics, covalent adaptable networks, thermosets, vitrimers, upcycling
论文来源:期刊
具体来源:Green Chemistry
发表时间:2021年

The huge amount of plastic waste is imperiling our daily life. Here, we designed a green and efficient large-scale one-pot method combining grafting and reversible cross-linking on a twin screw extruder. Post-consumer plastic bags were upcycled to covalent adaptable network (CAN) based on internally catalyzed anhydride monoesters transesterification, superior performance and reprocessability at elevated temperatures were achieved. This work provides a new idea for upcycling post-consumer polyolefin plastics, and the produced materials show great potential to be used in industrial scale.

论文链接:Upcycling of post-consumer polyolefin plastics to covalent adaptable networks via in situ continuous extrusion cross-linking - Green Chemistry (RSC Publishing)