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218. Graphene Liquid Marbles as Photothermal Miniature Reactors for Reaction Kinetics Modulation.
作者:W. Gao, H. K. Lee, J. Hobley, T. X. Liu*, I. Y. Phang*, X. Y. Ling*
关键字:Graphene, Liquid Marbles, Photothermal Miniature Reactors
论文来源:期刊
具体来源:Angew. Chem. Int. Ed., 2015, 54(13), 3993-3996.
发表时间:2015年
We demonstrate the fabrication of graphene liquid marbles as photothermal miniature reactors with precise temperature control for reaction kinetics modulation. Graphene liquid marbles show rapid and highly reproducible photothermal behavior while maintaining their excellent mechanical robustness. By tuning the applied laser power, swift regulation of graphene liquid marbles surface temperature between 21–135 oC and its encapsulated water temperature between 21–74 oC are demonstrated. The temperature regulation modulates the reaction kinetics in our graphene liquid marble, achieving a 12-fold superior reaction rate constant for methylene blue degradation than at room temperature.