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Synthesis and Characterization of Main Chain Aromatic Liquid Crystal Copolyesters with X-Shaped and Rod-Shaped Mesogenic Units
作者:Z.F.Li, L.Li, S.Y.Zhang, S.J.Zheng,S. K. Cao and L.T.Zhao,Q.F.Zhou**
关键字:liquid crystal polymer; X-shaped and rod-shaped mesogenic units; Aromatic copolyesters; Sythensis and characterization.
论文来源:期刊

A series of main chain liquid crystal aromatic copolyesters with X-shaped and rod-shaped mesogenic units were synthesized via solution condensation polymerizations of 4,4-(a,w-octanediolyloxy)-dibenzoyl dichlorides with 2,5-bis(p-octanoxy benzoyloxy)-hydroquinene and diphenol. All of the copolyesters showed thermotropic liquid crystalline behaviors through observations using DSC, polarized microscopy and X-ray diffraction. The melting point (Tm) and the isotropization temperature (Ti) change regularly with varying the content of dipheol unit in the copolymers.