29. (Small) Photo‐Responsive Self‐Assembly of an Azobenzene‐Ended Surfactant‐Encapsulated Polyoxometalate Complex for Modulating Catalytic Reactions
作者：Yang Yang, Liang Yue, Haolong Li, Eamonn Maher, Yongguang Li, Yizhan Wang, Lixin Wu,* Vivian Wing‐Wah
关键字：polyoxometalates, self-assembly, disassembly, photo-responsive, azobenzene
论文来源：期刊
具体来源：Small 2012, 8, 3105-3110
发表时间：2012年
The photo-responsive azobenzene-ended surfactant-encapsulated polyoxometalate (POM) complex is prepared. The photoswitchable assembly and disassembly of the complex are demonstrated in different polar solvents, driven by the photoisomerization of azobenzene group-induced polarity change. The reversible assembly and disassembly of the complex further facilitate the controllable oxidation reaction catalyzed by POM and the separation of POM-based homogeneous catalyst.
http://onlinelibrary.wiley.com/doi/10.1002/smll.201200768/abstract?deniedAccessCustomisedMessage=&userIsAuthenticated=false