Clusto-supramolecular block copolymers are synthesized by usingan anionic cluster [W6O19]2- as an ionic junction to link two cat-ionic terminated polystyrene chains. These polymers exhibit versa-tile self-assembly behaviours not only dependent on the molecularweight but also adaptive to the concentration and temperature.

Link to Polym. Chem. 2016, 7, 3216-3220.