5. (Adv. Mater.) A Highly Transparent and Luminescent Hybrid Based on the Copolymerization of Surfactant‐Encapsulated Polyoxometalate and Methyl Methacrylate
writer:Haolong Li, Wei Qi, Wen Li, Hang Sun, Weifeng Bu, Lixin Wu*
keywords:Europium complexes, Fluorescence, Hybrid materials, Inorganic–organic, Polyoxometalates
source:期刊
specific source:Advanced Materials 2005, 17, 2688-2692
Issue time:2005年
A polyoxometalate-based hybrid is produced by the copolymerization of a terminal-unsaturated surfactant- encapsulated polyoxometalate and methyl methacrylate. This hybrid exhibits flexible processability, high transparency of the polymer, and high fluorescence of the inorganic cluster (see Figure). The method presented in this paper provides general access to the fabrication of organic–inorganic electrostatic-complex-based materials in polymer matrices.