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30. Graphite oxide: a selective and highly efficient oxidant of thiols and sulfides
作者:D. R. Dreyer, H.-P. Jia, J. Geng, C. W. Bielawski,*
关键字:Graphene oxide,Heterogeneous catalysis,Hydrogen-peroxide,Room-temperature,Oxidation,Disulfides,Sulfoxides,Complexes,Chemistry,Oxygen
论文来源:期刊
具体来源:Org. Biomol. Chem., 2011, 9, 7292-7295
发表时间:2011年
The selective oxidation of thiols to disulfides and sulfides to sulfoxides using graphite oxide (GO), a heterogeneous carbocatalyst obtained from low cost, commercial starting materials is described. The aforementioned oxidation reactions were found to proceed rapidly (as short as 10 min in some cases) and in good yield (51-100%) (19 examples). No over-oxidation of the substrates was observed, and GO''''''''s heterogeneous nature facilitated isolation and purification of the target products.