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(Langmuir )Equilibrating Immigration and Anthracene-Maleimide-Based Diels? Alder-Trapping of Octylmaleimide in Mixed Photo-Cross-Linked Polymer Micelles
作者:Yan Liu, Min Tian, Huan Chang, Jinqiang Jiang,* Xiangyang Yan, Zhaotie Liu, and Zhongwen Liu
关键字:Equilibrating Immigration and Anthracene-Maleimide-Based Diels? Alder-Trapping of Octylmaleimide in Mixed Photo-Cross-Linked Polymer Micelles
论文来源:期刊
具体来源:Langmuir 2014, 30, 14782?14788
发表时间:2014年

It is possible that the hydrophobic guest within amphiphilic polymer micelles may leak out and be captured by other species before polymer micelles adhere to the desired focus because of the complexity in an actual release procedure, rendering the reduced efficiency of the nanocarrier system. To describe such a scenario, two watersoluble fluorescent amphiphilic random copolymers of PAV and PAA with photo-crosslinkable coumarin and anthracene pendants, respectively, were chosen to investigate the equilibrating immigration and maleimide-anthracene-based Diels?Alder-trapping of hydrophobic octylmaleimide guest from one type of photo-cross-linked polymer micelles of PAV85% to another of PAA66% in aqueous solution using the emission and absorption spectra techniques.