writer：Dai, L. W.; Lu, X. F.; Song, L. P.; Huang, Y. J.*; Liu, B. Q.; Zhang, L.; Zhang, J. W.; Wu, S.; Chen*,
keywords：1. Wang, L.; Jian, Y.; Le, X.; Lu, W.; Ma, C.; Zhang, J.; Huang, Y.; Huang, C.-F.; Chen, T., Actuating and memorizing bilayer hydrogels for a self-deformed shape memory function. Chem. Commun. 2018.
source：期刊
specific source：Adv. Mater. Interfaces
Issue time：2018年
Due to their abundant optical colors, durable color generation, and high refreshing rate, smart chromic nano-materials (SCNMs) have been employed in various applications. However, most SCNMs often require multi-component materials, precise morphology control, and complicated modulation to realize multicolor changes, which limits their widely practical applications. In our present study, we demonstrate a simple and effective strategy to achieve the flexible and cost-effective multicolor gold nanorods/polymer hybrid film, by tuning macroscopic oriented gold nanorods (Au NRs) in films and a synergy of polarization-dependent surface plasmon resonance. Au NRs were first functionalized with methoxypoly(ethylene glycol)thiol (mPEG-SH) to improve the compatibility, ensuring Au NRs can be homogenously dispersed in the polyvinyl alcohol (PVA) matrix with high particle density. The macroscopic oriented alignment of Au NRs can be achieved by the elongation of the PVA polymer molecular chains. Under different polarized excitation directions, the same strip of the hybrid film exhibits various colors including red, orange, yellow, and green. Therefore, our strategy provides a simple and powerful approach to achieve macroscopic oriented anisotropic nanoparticles in the polymer matrix, and the resultant hybrid films are promising in various practical applications such as color displays, optical devices, and plasmonic biosensors