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Radicamines A and B: Synthesis and Revision of the Absolute Configuration
作者:Chu-Yi Yu*, Mu-Hua Huang
关键字:radicamines, synthesis, absolute configuration
论文来源:期刊
具体来源:Organic Letters
发表时间:2006年

Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.