Rhodium-catalyzed regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands.
作者：Guodu Liu, Zhao Li, Huiling Geng,* Xumu Zhang.*
关键字：regioselective hydroaminomethylation
论文来源：期刊
具体来源：Catal. Sci. Technol. 2014, 4, 917-921. (DOI: 10.1039/C3CY01069D, communication, IF = 5.726, Citation
发表时间：2014年
A concise and elegant protocol was developed to prepare linear amines by regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands. It has been documented that the reactivity of the ligand is modulated by the substituent of the
biphenylphosphane moiety. Ligand L5 containing electron-donating groups exhibited the highest reactivity, with up to 70.9 n/i ratio and 99.5% amine selectivity for 1-pentene and a 31.3 n/i ratio and 97.9% amine selectivity for 1-hexene.