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65. [Polymer] Joint double-network hydrogels with excellent mechanical performance
作者:Meng Zhang, Xiuyan Ren, Lijie Duan, Guanghui Gao
关键字:Double network Joint double network High mechanical properties
论文来源:期刊
发表时间:2018年

Based on the tough double-network hydrogel, a further crosslinked DN network hydrogel was developed and

named joint double network (JDN) hydrogel. The JDN hydrogel consisting of ionically cross-linked sodium

alginate (SA) as the first network, the chemically cross-linked poly (acrylamide-acrylic acid) (PAMAAc) as the

second network and both of them combined together by ferric ions. As a result, SA/PAMAAc-Fe3+ hydrogels

exhibited high mechanical strength with tensile stress of 1.26 MPa and tensile strain of 653%. Ultraviolet–visible

spectroscopy, rheological and swelling tests also illustrated that the JDN structure greatly improved the mechanical

properties of hydrogels because of close integration of internal networks. Moreover, the SA/PAMAAc-

Fe3+ JDN hydrogel also owned high water content of 85%, free-plasticity, and excellent electrical property,

which allowed it to be easily molded various shapes for tough electronic devices, flexible electrodes, and

wearable equipment.