作者：Yang, CH (Yang, Chenghan) ; Mao, CF (Mao, Chunfeng) ; Deng, QH (Deng, Qinghua) ; Yang, Y (Yang, Yong
关键字：Covalent organic frameworksOne -pot synthesisFlavoneOrganic catalysisAu coordination
论文来源：期刊
发表时间：2023年
Covalent organic frameworks (COFs) are excellent candidates for rationally designed metal-coordinated catalysts due to their porous structures and adjustable organic building blocks. In this work, a twodimensional (2D) COF with novel fxt topology was synthesized. The newly devised COF had been fully characterized by a range of spectroscopic and microscopic techniques. The COF was further metallized by the gold species to form a heterogeneous catalyst that enabled the one-pot synthesis of flavone and its derivatives. The Au@COF catalyst showed high catalytic activity and good recyclability. This work demonstrates the great potential of metallized COFs with unique well-defined pores in organic catalysis.& COPY; 2023 Elsevier Inc. All rights reserved.