作者：Nan, QL (Nan, Qiuli) [1] ; Song, L (Song, Li) [2] ; Zhou, YM (Zhou, Yuming) [1] , [2] ; Yao, QZ (Yao
关键字：Acid solutions,corrosion inhibitors,electrochemical measurements
论文来源：期刊
发表时间：2020年
The inhibition effect of three inhibitors with different chain lengths of their ether groups on Q235 steel in 0.5 M HCl solution at 318 K was determined by means of weight loss measurement, electrochemical methods (Tafel and EIS) and surface analysis (SEM). Moreover, the further study of corrosion inhibition mechanism was also conducted by computational methods (Quantum chemical calculations and Molecular dynamics simulations). Results reveal that the three inhibitors exhibit an excellent inhibition performance for carbon steel, and the corrosion inhibition efficiency of the three inhibitors increases with the increase of the chain length, which favors the formation of a protection film adsorbed on the surface. Analysis of polarization data informs that the adsorption type of three inhibitors basically obeys the Langmuir monolayer adsorption, which is mainly of chemisorptive nature. Computational methods also tell that the three inhibitors possess a high reactivity and strong interaction with the iron surface, furthermore, the interaction is increased with the increase of the chain length of three inhibitors. The conclusion is in good agreement with the experimental results.