Charge-Transfer Complexation Mechanism of Poly(4-vinylpyridine)/[6,6]- Phenyl-C61-butyric Acid Methyl Ester in DMF Solution
writer：Guangmin Wei; Dongdong Yao; Zhiyong Li; Ye Huang; He Cheng;* Charles C. Han*
keywords：charge transfer complexaton
source：期刊
specific source：Macromolecules, 46, 1212-1220, 2013
Issue time：2013年
Small-angle
neutron scattering was used to investigate
poly(N-isopropylacrylamide) (PNIPAM) polymer solutions in d-water/d-ethanol mixtures. A wide poor-solvent region was observed for mixtures near 60% d-water/40% dethanol mixture. Spinodal lines were determined, permitting a mapping of the mixing/demixing regions of the phase diagram which comprises two main branches: the left branch (with mostly d-ethanol) where phase separation occurs upon cooling (UCST) and the right branch (with mostly d-water) where phase separation occurs upon heating (LCST). The ternary random phase approximation model was used to analyze SANS data. Three Flory?Huggins interaction parameters (PNIPAM/d-water, PNIPAM/d-ethanol and d-water/d-ethanol) were obtained. These display the reassuring 1/T behavior but show strong
dependence on d-water/d-ethanol fraction. The conformation of polymer chains was determined by monitoring of the radius
of gyration. Chains tend to swell with increasing temperature except close to the boundary of the left branch of the phase
diagram (40% d-water) where they are observed to shrink.