作者：Yugao Guo*, He Zhao, Yelin Han, Xia Liu, Shan Guan, Qingyin Zhang, Xihui Bian
关键字：Cation exchange fiber, Ultraviolet and visible spectrophotometer, Solid phase extraction, Partial least squares, Heavy metal ions
论文来源：期刊
具体来源：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
发表时间：2017年
A simultaneous spectrophotometric determination method for trace heavy metal ions based on solid-phase extraction coupled with partial least squares approaches was developed. In the proposed method, trace metal ions in aqueous samples were adsorbed by cation exchange fibers and desorbed by acidic solution from the fibers. After the ion preconcentration process, the enriched solution was detected by ultraviolet and visible spectrophotometer (UV-Vis). Then, the concentration of heavy metal ions were quantified by analyzing ultraviolet and visible spectrum with the help of partial least squares (PLS) approaches. Under the optimal conditions of operation time, flow rate and detection parameters, the overlapped absorption peaks of mixed ions were obtained. The experimental data showed that the concentration, which can be calculated through chemometrics method, of each metal ion increased significantly. The heavy metal ions can be enriched more than 80-fold. The limits of detection (LOD) for the target analytes of copper ions (Cu2+), cobalt ions (Co2+) and nickel ions (Ni2+) mixture was 0.10 mu g L-1, 0.15 mu g L-1 and 0.13 mu g L-1, respectively. The relative standard deviations (RSD) were less than 5%. The performance of the solid-phase extraction can enrich the ions efficiently and the combined method of spectrophotometric detection and PLS can evaluate the ions concentration accurately. The work proposed here is an interesting and promising attempt for the trace ions determination in water samples and will have much more applied field.