Links
Contact Info.
  • Address:加拿大魁北克省蒙特利尔
  • Zip:无
  • Tel:(514) 848-2424 ext.5611
  • Fax:
  • Email:zhibin.ye@concordia.ca
Current Location :> Home > Publications > Text
A conveniently synthesized polyethylene gel encapsulating palladium nanoparticles as a reusable high-performance catalyst for Heck and Suzuki coupling reactions
writer:P. Liu, Z. Dong, Z. Ye*, W.-J. Wang*, B.-G. Li
keywords:无
source:期刊
specific source:Journal of Materials Chemistry A
Issue time:2013年

The synthesis of a polyethylene (PE) gel containing self-incarcerated palladium(0) nanoparticles is described. The PE gel matrix without any special functionality was synthesized by one-pot chain walking copolymerization of ethylene and 1,6-hexanediol diacrylate facilitated by a Pd–diimine complex (1). The Pd(II) species from 1 were immobilized in situ onto the gel matrix and further reduced to Pd(0) nanoparticles as a result of catalyst 1 deactivation during polymerization and methanol (a reducer) washing in the polymer purification process. The resulting Pd-containing PE gel (2) is shown to be a high-performance and facilely reusable heterogeneous catalyst for the Heck and Suzuki coupling reactions of iodobenzene or aryl bromides. An average TOF of 460 h1 was achieved with an average 0.57 ppm Pd leaching in each cycle of the Heck reaction of iodobenzene when the PE gel 2 was recycled 10 times. A maximum TOF of 3.33  104 h1 was reached and less than 0.64 ppm of Pd was leached in the Suzuki reactions of aryl bromides with water as solvent.