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A Pd?diimine catalytic inimer for synthesis of polyethylenes of hyperbranched-on-hyperbranched and star architectures
writer:L. Xu, Z. Ye*
keywords:无
source:期刊
specific source:Chemical Communications
Issue time:2013年
A Pd-diimine catalytic inimer containing uniquely catalytic, initiating, and monomeric functionalities in one catalyst molecule is designed. It enables the first self-condensing vinyl copolymerization of ethylene, leading to polyethylenes of a hyperbranched-on-hyperbranched architecture. Meanwhile, it also facilitates the synthesis of star polyethylenes by tandem UV-coordinative polymerization.