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Homogeneous polyhedral oligomeric silsesquioxane (POSS)-supported Pd-diimine complex and synthesis of polyethylenes end-tethered with a POSS nanoparticle via ethylene "living" polymerization
writer:Y. Zhang, Z. Ye*
keywords:无
source:期刊
specific source:Chemical Communications
Issue time:2008年

A POSS-supported Pd–diimine complex, an homogeneous analog of a supported catalyst, was synthesized and applied for the unique synthesis of narrow-distributed polyethylene chains containing an end-tethered POSS nanoparticle by ethylene ‘‘living’’ polymerization.