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Metallic Nanoparticles with High Catalytic Properties Stabilized by Functional Polymer Microspheres and Microcapsules
This paper described the in-situ synthesis of the polymer microsphere-stabilized metallic nanocolloids via the reduction of HAuCl4 with NaBH4 as reductant and the mechanism for such stabilization.
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6611.html |
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Distillation-precipitation polymerization as a novel technique for the preparation of monodisperse functional polymer microspheres
The synthesis of monodisperse polymer microspheres and the inorganic/polymer core-shell composite/hybrid microsphere is summarized.
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6610.html |
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Hydrogenation of o-Chloronitrobenzene over Polymer-stabilized Palladium-Platinum Bimetallic Colloidal Clusters
Hydrogenation of o-chloronitrobenzene o-CNB. has been studied in methanol at 303 K and atmospheric pressure over polyvinylpyrrolidone-stabilized palladium–platinum PVP-PdrPt. bimetallic colloidal clusters. The catalytic properties for the hydrogenation of o-CNB to o-chloroaniline o-CAN. are found to depend on the metal composition of the bimetallic
clusters. All the bimetallic clusters are mor...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6601.html |
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Synthesis of Monodisperse CdS/SiO2/Polymer Tri-layer Fluorescent Microspheres
Tri-layer CdS/SiO2/polymer hybrid nanospheres were synthesized by distillation precipitation polymerization of either ethyleneglycol dimethacrylate (EGDMA) or EGDMA together with comonomers having different functional groups, such as methacrylic acid, 4-vinylpyridine and 2-hydroxyethylmethacrylate, in the presence of 3-(methacryloxy)propyl trimethoxysilane (MPS)-modified CdS/SiO2 nanoparticles a...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6594.html |
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The Magnetic Polymer Microsphere Stabilized Nano-Metallic Colloids as A Facilely Recoverable Catalyst
Magnetically responsive hierarchical magnetite/silica/poly(ethyleneglycol dimethacrylate-co-4-vinylpyridine) (Fe3O4/SiO2/P(EGDMA-co-VPy)) tri-layer microspheres were used as stabilizers for gold metallic nanocolloids as a facilely recoverable catalyst with the reduction of 4-nitrophenol to 4-aminophenol as a model reaction. The magnetic microsphere
stabilized gold metallic nanocolloids were prep...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6593.html |
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Synthesis of Monodisperse Hollow Polymer Microspheres with Functional Groups by Distillation Precipitation Polymerization
Monodisperse hollow polymer microspheres having various functional groups on the shell-layer, such as carboxylic acid, pyridyl and amide, were prepared by two-stage distillation precipitation polymerization in neat acetonitrile in the absence of any stabilizer or additive, during which monodisperse poly(methacrylic acid) (PMAA) afforded from the
first-stage polymerization was utilized as the seeds...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6591.html |
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Preparation of Narrow or Monodisperse Polymer Microspheres by Distillation-precipitation Polymerization
Narrow- or monodisperse poly(divinylbenzene-co-acrylonitrile) (poly(DVB-co-AN))
microspheres with reactive cyano group were prepared by distillation-precipitation
polymerization of divinylbenzene (DVB) and acrylonitrile (AN) in neat acetonitrile
with 2,2′-azobis(isobutyronitrile) (AIBN) as initiator in the absence of any stabilizer
or additive without stirring. The effects of the comonomer feed o...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6582.html |
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Synthesis of Monodisperse Titania/Polymer Core-shell Hybrid Microspheres
Monodisperse titania/polymer core-shell microspheres were prepared by a two-stage reaction with titania as core and poly(ethyleneglycol dimethacrylate) (PEGDMA)
as shell, in which the titania cores were synthesized by a sol-gel method and subsequently grafted with 3-trimethoxysilyl methacrylate as the first-stage reaction to incorporate the vinyl groups on the surface of inorganic core. The PEGDMA...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6572.html |
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Synthesis of Hollow Fluorescent Polymer Microspheres with Movable Magnetic Cores
Low-dispersity hollow poly[(ethyleneglycol dimethacrylate)-co-(N-vinylcarbazole)] (P(EGDMA-co-NVCz)) fluorescent microspheres with movable magnetic cores were prepared by quantitative removal of the silica component in hydrofluoric acid aqueous solution from the corresponding magnetite/silica/P(EGDMA-co-NVCz) tri-layer hybrid microspheres. The tri-layer microspheres with magnetic cores and fluores...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6566.html |
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Preparation of Monodisperse Hydrophilic Polymer Microspheres with N,N?-Methylenebisacrylamide as Crosslinker by Distillation Precipitation Polymerization
Highly crosslinked cauliflower-like poly(N,N-methylenebisacrylamide) particles were prepared by distillation precipitation polymerization in neat acetonitrile with 2,2-azobisisobutyronitrile as initiator. Monodisperse hydrophilic polymer microspheres with various functional groups, such as amide, pyrrolidone and carboxylic acid, with a spherical shape and smooth surface in the size range 120–60...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6565.html |
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