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  • Hollow Cholesteric Liquid Crystal Elastomer Fiber with Synergistically Enhanced Resilience and Mechanochromic Sensitivity
  • 来源:王雯雯教授个人网站 2025-07-04
  • Mechanochromic cholesteric liquid crystal elastomers (CLCE) are

    unique anisotropic rubbers with the programmable optical properties in response

    to external stimuli, bringing considerable interests in display, sensing and smart

    textiles. However, creating mechanochromic CLCE fibers with high sensitivity,

    excellent resilience and stable color-changing reversibility is still a

    challenge. This work describes mechanochromic CLCE symmetric

    hollow fibers with excellent radial helix alignment prepared by solvent

    evaporation-induced assembly and template assistance. The cylindrical symmetry

    renders the response identical in all directions perpendicular to fiber axis. The

    hollow fibers show mechanochromic ability in full visible spectrum, a large

    wavelength blueshift of 2.25 nm·%-1 under low strain. Excellent

    mechanochromic reversibility of 100 cycles and resilience are both devoted by cross-linking

    structure in the wall layer, which also contributes to reversible orientation-recovery

    of liquid crystal units during stretching-recovery cycles. Numerical models and

    experimental measurements demonstrate the hollow structure enabled fibers to

    produce air pressure inside when being stretched, and the fiber wall layer is

    subjected to greater stress compared to solid fibers, thus achieving high

    mechanochromic sensitivity. In addition, hollow fiber can still change

    color when subjected to the expansion stress inside the cavity, and

    programmable information display in fabric prolongs its application in intelligent

    textiles.

  • [来源:中国聚合物网]
  • 了解更多请进入: 王雯雯教授个人网站
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