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  • Core-Cross-Linked Micellar Nanoreactors for Biaryl Synthesis in Water: Influence of Topological Structures on Catalytic Activity
  • 来源:胡克苓xx个人网站 2025-05-23
  • Multiple block copolymers bearing PDMAEMA (poly(2-(dimethylamino)ethyl methacrylate), PLMA (poly(lauryl methacrylate), and PAMA (poly(allyl methacrylate) segments are synthesized via RAFT (reversibleaddition-fragmentation chain transfer) polymerization. Manipulating the cross-linkage of PAMA in the specific domain of polymeric assemblies affords micellar nanoreactors with different topological structures. After embedded with Pd NPs (nanoparticles) in the corona layer, the core-cross-linked micelles demonstrate profound catalytic activity and structural stability in the aqueous Suzuki–Miyaura coupling of aryl bromides with aryl boronic acids.



  • [来源:中国聚合物网]
  • 了解更多请进入: 胡克苓xx个人网站
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