Owing to their rich structural chemistry and unique electrochemical properties, vanadium-based materials, especially the low-dimensional ones, are showing promising applications in energy storage and conversion. In this invited review, low-dimensional vanadium-based materials (including 0D, 1D, and 2D nanostructures of vanadium-containing oxides, polyanions, and mixed-polyanions) and their emerging applications in advanced alkali-metal-ion batteries (e.g., Li-ion, Na-ion, and K-ion batteries) are systematically summarized. Future development trends, challenges, solutions, and perspectives are discussed and proposed. Mechanisms and new insights are also given for the development of advanced vanadium-based materials in high-performance energy storage and conversion.

由于其丰富的结构化学和独特的电化学性能，钒基材料，特别是低维材料，在能量存储和转换方面显示出广阔的应用前景。在这篇特邀综述中，低维钒基材料（包括含钒氧化物、聚阴离子和混合聚阴离子的0D、1D和2D纳米结构）及其在先进碱金属离子电池（例如Li离子、钠离子和钾离子电池）进行了系统总结。讨论并提出了未来的发展趋势、挑战、解决方案和前景。还为高性能能量存储和转换领域先进钒基材料的开发提供了机制和新见解。

期刊论文全文链接：https://www.mdpi.com/1996-1944/17/3/587