首页
最新动态 交流合作 科研项目 论文著作 精彩瞬间 招生招聘
  • Lighted up by hydrogen-bonding: luminescence behavior and applications of AIEgen-doped interpenetrating network hydrogel
  • 来源:赵传壮教授个人网站 2023-07-04
  • The interaction between the aggregation-induced emissive (AIE) luminogens (AIEgen) and the polymer is the key scientific question in the design of functional AIE hydrogels. In this study, we report the AIE behavior of a poly(acrylic acid) (PAAc) and poly(acrylamide) (PAAm) interpenetrating network (IPN) hydrogel doped with tetra-cationic tetraphenylethene (TCTPE). The cationic AIEgen can bind with PAAc through ionic interaction, while PAAc and PAAm chains can associate with each other through hydrogen-bonds (H-bonds). These two interactions can restrict the intramolecular rotation and thus activate the luminescence of the AIEgen. The PAAc-PAAm H-bonds can be broken by increasing temperature or pH, restoring the intramolecular rotation of the AIEgen and quenching the fluorescence of the hydrogel. Therefore, the TCTPE-doped IPN hydrogel is designed as temperature- and pH-sensitive displayers which can record information imprinted by photo-printing or iono-printing with good switchability and reversibility. Another application of this TCTPE-doped hydrogel is demonstrated as a luminescent soft actuator, which has fast shape deformation and editable fluorescence pattern. The above results reveal a pathway to tune the emission behavior through tuning polymer-polymer and polymer-AIEgen interactions, which may inspire new design strategies of aggregation-induced emissive polymers and broaden their applications.
  • [来源:中国聚合物网]
  • 了解更多请进入: 赵传壮教授个人网站
相关新闻
  • · Design of a UCST Polymer with Strong Hydrogen Bonds and Reactive Moieties for Facile Polymer-Protein Hybridization
  • · Poly(N-acryloyl glycinamide-co-N-acryloxysuccinimide) Nanoparticles: Tunable Thermo-Responsiveness and Improved Bio-Interfacial Adhesion for Cell Function Regulation
  • · Cold-induced shape memory hydrogels for strong and programmable artificial muscles
  • · Biomimetic Self-Deformation of Polymer Interpenetrating Network with Stretch-Induced Anisotropicity

关于我们  |  联系我们  

网站:中国聚合物网

polymer.cn Copyright ©2017