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  • Dewetting and phase behaviors for ultrathin films of polymer blend.
  • 来源:廖永贵副教授个人网站 2009-09-22
  • Dynamics of dewetting and phase separation in ultrathin films (thickness is ca. one radius of gyration, ~ 1 Rg) of poly(methyl methacrylate) (PMMA) and poly(styreneran-acrylonitrile) (SAN) blends on Si substrate has been studied by in situ atomic force microscopy (AFM). In the miscible region, a ‘‘spinodal-like’’ dewetting driven by a composition fluctuation recently predicted by Wensink and Je´roˆme (Langmuir 2002, 18, 413) occurs. In the two-phase region, the dewetting of the whole film is followed by phase separation in the droplets, coupling with the wetting of the substrate by the PMMA extracted by the strong attractive interaction between them.

  • [来源:中国聚合物网]
  • 了解更多请进入: 廖永贵副教授个人网站
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