JMST特邀高被引综述文章“面向极端高温环境应用的微/纳米多尺度强韧化复合材料及其涂层研究进展”及其新近相关工作概览

https://mp.weixin.qq.com/s/cC-xLvDYP9Kl2JaDFf-gmw

https://doi.org/10.1016/j.jmst.2021.03.076

https://linkinghub.elsevier.com/retrieve/pii/S1005030221004527

https://doi.org/10.1016/j.jmst.2021.03.076

西北工大付前刚教授：多主元高熵超高温陶瓷改性热防护涂层2022-12-29 19:23:19　来源: 材料学网

https://www.163.com/dy/article/HPPE40A70536M4GO.html

西北工业大学陶瓷顶刊：原位硼/碳热还原法结合气相反应熔渗法制备极端环境用碳基复合材料多主元高熵超高温陶瓷改性热防护涂层

https://www.sciencedirect.com/science/article/pii/S0272884222001407?via%3Dihub

https://www.sciencedirect.com/science/article/pii/S0272884222020144

2022年1月，西北工业大学（Northwestern Polytechnical University，昵称“西瓜大”，简称“西工大”，是中华人民共和国工业和信息化部直属，我国唯一一所以同时发展航空、航天、航海（简称“三航”）工程教育和科学研究为特色的全国重点大学）李贺军院士（https://mp.weixin.qq.com/s/Sh9swmi3c58x7lqe_OIttg）、国家杰青付前刚教授（https://mp.weixin.qq.com/s/plB42-khi1SNBS_uxlDGPQ）等领衔的陕西省纤维增强轻质复合材料重点实验室（Shaanxi Key Laboratory of Fiber Reinforced Light Composite Materials）在材料领域著名顶级期刊《Journal of Materials Science & Technology》（简称《JMST》）发表了主题为“面向极端高温环境应用的微/纳米多尺度强韧化C/C复合材料（炭炭复合材料-隐藏的实力https://mp.weixin.qq.com/s/UglDya1J9-5eNqTIwsDEjw）及其涂层研究进展”的特邀综述文章（2022年96期，31-68页），并被遴选为封面文章（https://mp.weixin.qq.com/s/m1_FfV8KorBP_MiY-N23Ag）。

参考文献：Fu Qiangang 1*, Zhang Pei 1, Zhuang Lei, Zhou Lei, Zhang Jiaping, Wang Jie, Hou Xianghui, Riedel Ralf, Li Hejun *, Micro/nano multiscale reinforcing strategies toward extreme high-temperature applications: take carbon/carbon composites and their coatings as the examples, Journal of Materials Science & Technology, 2022, 96: 31-68. 10.1016/j.jmst.2021.03.076

本综述系统地评述了微/纳多尺度强韧化极端苛刻环境用耐高温氧化/抗烧蚀复合材料相关重要新进展，同时对其强韧化机理和效果着重进行了论述。所述微/纳多尺度强韧化材料包括纳米颗粒(简写为NPs)，碳纳米管/碳纳米纤维(简写为CNT/CNFs)，纳米线(简写为NWs)，晶须，石墨烯，陶瓷纤维和混杂多尺度微/纳结构等。综述包含综合表格13个，大图39幅，参考文献243条，基于本科研团队十多年的研究工作及相关课题组、研究单位的成果综述而成，总计逾两万字。相关研究工作得到了国家重点研发计划、凝固技术国家重点实验室基金、111创新引智基地项目、陕西省创新人才推进计划基金、超高温结构复合材料重点实验室基金、GF基金、国家自然基金委和陕西省教育厅科研计划项目等的经费支持。

与该综述文章相关专题、主题涉及以下多个方面：微（石墨烯、晶须、短纤维）纳（纳米颗粒、纳米线、纳米管）多尺度材料，超高温陶瓷、强韧化，轻质高强复合材料，复合涂层，腐蚀、烧蚀与氧化，抗热震，氧化防护能力，核壳网络结构，原位生长，C/C复合材料，纳米陶瓷，机械性能，碳纳米管等等。文章发表后引起相关领域关注，感谢相关研究学者的持续关注。目前本文Scopus、web of science - Clarivate、Researchgate引用超过70条。

发文前该综述已被国内外多位专家、学者在Composites Science and Technology、Advanced Functional Materials、Corrosion Science、无机材料学报Journal Of Inorganic Materials、Advances in Materials Science and Engineering、Reviews on Advanced Materials Science、Carbon、Applied Physics Letters、Science China Materials、Engineering Failure Analysis、ACS Nano、JMST、Materials Characterization、Metals、Ceramics International、Materials、Journal of the European Ceramic Society、Surface and Coatings Technology、Journal of Materiomics、Journal of the American Ceramic Society、Synthesis and Sintering、Materials Science and Engineering: A、Composites Part A: Applied Science and Manufacturing、Composites Part B: Engineering、Composites Structures等数十种期刊发表的53篇文章（包括预印本Rreprint）引用。部分关键施引文献（其中53篇已经在文章“JMST综述“面向极端高温环境应用的微/纳米多尺度强韧化复合材料及其涂层研究进展”及其新近相关工作概览”（下图所示https://mp.weixin.qq.com/s/cC-xLvDYP9Kl2JaDFf-gmw）中介绍）如下（附有图片摘要Graphical abstract等信息），于此将其他新近引用本综述的70余篇文献的关键信息分享，以飨读者，共同学习、促进相关工程科学领域的认识（所列文章均已经在线正式发表，网络上可检索，如有侵权或交流请联系作者，QQ781520976，谢谢关注）：

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22. Yao Guo, Leilei Zhang, Qiang Song, Ruonan Zhang, Fei Zhao, Wei Li, Hongchao Sheng, Xianghui Hou, Hejun Li. Simultaneously enhancing mechanical and tribological properties of carbon fiber composites by grafting SiC hexagonal nanopyramids for brake disk application. Journal of Materials Science & Technology (IF 8.067) Pub Date : 2022-03-12 ,https://doi.org/10.1016/j.jmst.2021.12.050

23. Dongdong Yang, Shun Dong, Changqing Hong, Xinghong Zhang. Preparation, modification, and coating for carbon-bonded carbon fiber composites: A review.Ceramics International ( IF 4.527 ) Pub Date : 2022-03-11 , https://doi.org/10.1016/j.ceramint.2022.03.055

24. Yin X, Han L, Liu H, et al. Recent progress in 1D nanostructures reinforced carbon/carbon composites[J]. Advanced Functional Materials, 2022, 32(35): 2204965. https://doi.org/10.1002/adfm.202204965 （通讯单位：西北工业大学，第一作者：第一作者：殷学民博士后 通讯作者：航空学院李霓教授、宋强研究员、张雨雷教授）

Graphical Fig. 24. Skeleton diagram of design, fabrication, and properties of 1D nanostructures reinforced C/C composites.

25. Xiao C, Song Q, Shen Q, et al. Understanding on interlaminar nano-reinforcement induced mechanical performance improvement of carbon/carbon composites after silicon infiltration[J]. Composites Part B: Engineering, 2022, 239: 109946. https://doi.org/10.1016/j.compositesb.2022.109946 （通讯单位：西北工业大学，第一作者：肖才湘博士，通讯作者：宋强研究院）

Graphical Fig. 25. Schematic illustration of overall fabrication processes. (a) The plain weave carbon fiber clothes were coated with SiC nanowire by electrophoresis deposition technique as a hybrid fabric. (b) The modified carbon fiber clothes were layered up to densify with PyC through (isothermal chemical vapor deposition) ICVI method. (c) The densified SiCNW–C/C composites were coated on SiC by pack cementation.

26. Wang R, Li N, Zhang J, et al. Ablation behavior of sharp leading-edge C/C-ZrC-SiC composites using 3000° C oxyacetylene torch[J]. Corrosion Science, 2022, 206: 110551. https://doi.org/10.1016/j.corsci.2022.110551（通讯单位：西北工业大学，第一作者：王瑞宁硕士，通讯作者：航空学院李霓教授、付前刚教授）

Graphical Fig. 26. Preparation process, microstructure, mechanical property and ablation performance and mechanisms of C/C-ZrC-SiC composites

27. Chen B W, Ni D W, Lu J, et al. Long-term and cyclic ablation behavior of La2O3 modified Cf/ZrB2-SiC composites at 2500℃[J]. Corrosion Science, 2022, 206: 110538. https://doi.org/10.1016/j.corsci.2022.110538 （通讯单位：中科院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室，第一作者：陈博文博士，通讯作者：董绍明院士、倪德伟研究员）

Graphical Fig. 27. Phase diagrams of ZrO2-La2O3 (a) and La2O3-SiO2 (b)

28. Zheng L, Luo X, Fang C, et al. Ablation behaviour and mechanism of Mg-modified ZrC-SiC composite in plasma ablation flame[J]. Corrosion Science, 2022, 206: 110523. https://doi.org/10.1016/j.corsci.2022.110523 （通讯单位：中南大学轻质高强结构材料国家级重点实验室，第一作者：Lei Zheng博士，通讯作者：张明瑜教授、黄启忠教授）

Graphical Fig. 28. Schematic diagram showing the preparation of ZS and ZSM composites.

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Graphical Fig. 29. (a) Schematic illustration of the microstructure evolution of the HfB2-SiC/SiC coating.

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Graphical Fig. 30. Schematic diagram of impacted SiCnws@PyC/HfC and SiCnws@BN/HfC coatings during ablation process.

32. Li J, Zhang Y, Lv J, et al. Sealing role of Ti-rich phase in HfC-ZrC-TiC coating for C/C composites during ablation above 2100° C[J]. Corrosion Science, 2022, 205: 110474. https://doi.org/10.1016/j.corsci.2022.110474（通讯单位：西北工业大学，第一作者：李嘉晨博士，通讯作者：张雨雷教授）

Graphical Fig. 31. Schematic of the ablation mechanism of the HfC-ZrC-TiC coating.

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Graphical Fig. 32. Schematics showing the ablation in needled fiber (a) and nonwoven cloth (b) zones of the composites produced with CeCl3 addition.

34. Yan N, Zhang J, Liu T, et al. One-step preparation and ablation behavior of ZrC-SiC-Si coating for nose-shaped ZrC/C composites with gradient pore structure by vapor silicon infiltration[J]. Corrosion Science, 2022, 206: 110505. https://doi.org/10.1016/j.corsci.2022.110505（通讯单位：西北工业大学，第一作者：闫宁宁博士，通讯作者：张佳平副教授）

Graphical Fig. 33. Macrographs, surface and back temperature curves and simulation results of the nose-shaped ZrC/CGS-ZrC-SiC-Si composite during ablation for 40?s using oxyacetylene torch. (a) Macrograph during ablation, (b) Macrographs of specimens before and after ablation, (c) Surface temperature versus time curves, (d) Back temperature versus time curves, (e) Actual and simulated temperature curves, (f) Temperature distribution diagram after ablation for 40?s, (g) Temperature distribution diagram after cooling for 3?s, (h) The calculated Von Mises stress field at 43?s (Local region).

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Graphical Fig. 34. Macroscopic photographs and microscopic morphologies of HEFO powders after acid corrosion: (a) microscopic morphologies of untreated HEFO powders after acid corrosion; (b) local enlargement of Fig. 10a; (c) microscopic morphologies of annealed HEFO powders at 1473?K after acid corrosion; (d) local enlargement of Fig. 10c.

36. Sun J, Wang Y, Zhang Y, et al. Microstructure and mechanical properties of C/C composites modified by single-source precursor derived ceramics[J]. Journal of the European Ceramic Society, 2022, 42(13): 5419-5431. https://doi.org/10.1016/j.jeurceramsoc.2022.06.036（通讯单位：西北工业大学，第一作者：王雨祺博士，通讯作者：孙佳副教授）

Graphical Fig. 35. Failure mechanism model of C/C-PDC-NCs after pyrolysis at 1100?°C and subsequent annealing at 1500?°C: (a) C/C-SiC(N)-NCs; (b) C/C-SiC(N)/TiC-NCs-a; (c) C/C-SiC(N)/TiC-NCs-b. The black dots in (b, c) represent the pre-existing microcracks.

37. Zhu X, Zhang Y, Zhang J, et al. Microstructure evolution and oxidation mechanism of HfB2-SiC coating on SiC-coated C/C composites at 1173 K and 1773 K[J]. Ceramics International, 2022, 48(20): 30807-30816. https://doi.org/10.1016/j.ceramint.2022.07.034（通讯单位：西北工业大学，第一作者：朱肖飞博士，通讯作者：张雨雷教授）

Graphical Fig. 36. XPS patterns of 50 wt% HfB2-SiC coating after oxidation at 1173 K: (a) survey XPS spectra; (b) B 1s spectra; (c) Si 2p spectra.

38. Wang C, Fu Q, Zhou L. Significant increase in mechanical performance of the C/C-Mo joint by controlling the interfacial defects[J]. Materials Characterization, 2022, 193: 112275. https://doi.org/10.1016/j.matchar.2022.112275（通讯单位：西北工业大学，第一作者：王琛博士，通讯作者：付前刚教授）

Graphical Fig. 37. Schematic diagram of sample fabricating (a) and shear strength testing equipments (b).

38. Zhang P, Cheng C, Xu M, et al. High-entropy (Hf0. 25Zr0. 25Ti0. 25Cr0. 25) B2 ceramic incorporated SiC-Si composite coating to protect C/C composites against ablation above 2400 K[J]. Ceramics International, 2022. https://doi.org/10.1016/j.ceramint.2022.06.022（通讯单位：西北工业大学，第一作者：西安航天动力研究所张佩博士、工程师，通讯作者：付前刚教授）

Graphical Fig. 38. Ablation performance and mechnisms of the High-entropy (Hf0. 25Zr0. 25Ti0. 25Cr0. 25) B2 ceramic incorporated SiC-Si composite coating

39. Chen B W, Ni D W, Lu J, et al. Microstructure and mechanical behaviors of 2D-Cf/ZrB2-SiC composites at elevated temperatures[J]. Journal of the European Ceramic Society, 2022, 42(13), 5410-5418. https://doi.org/10.1016/j.jeurceramsoc.2022.05.063（通讯单位：中科院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室，第一作者：陈博文博士，通讯作者：董绍明院士、倪德伟研究员）

Graphical Fig. 39. FT-IR spectra of the pyrolyzed PCS (a), XRD patterns of the 2D-Cf/ZrB2-SiC composites after heat treatment at different temperatures (b), TEM and EDS spectra of raw ZrB2 powders (c), and TG-MS-Temperature curves of the 2D-Cf/ZrB2-SiC composites (d).

40. Chen Y, Wang P, Ren X, et al. Oxidation of TaB2-SiC coatings prepared by spark plasma sintering and effect of pre-oxidation treatments[J]. Journal of the European Ceramic Society, 2022. Volume 42, Issue 13, October 2022, Pages 5238-5248. https://doi.org/10.1016/j.jeurceramsoc.2022.06.003 （通讯单位：中国矿业大学材料科学与物理学院、西安科技大学材料科学与工程学院，第一作者：Yuexing Chen博士、王佩佩副教授，通讯作者：任宣儒副教授、Chunmin Yang副教授）

Graphical Fig. 40. (a) XRD patterns of the TaB2-SiC coatings oxidized at 1500?°C, (b) Gibbs free energy of the oxidation reactions R1-R7 at different temperatures.

41. Shi H, Zhang M, Zhou L, et al. Improved oxidation protective ability of SHS powder-synthesized ZrB2-MoSi2-SiC-Si coating on carbon/carbon composites[J]. Surface and Coatings Technology, 2022, 447: 128838. https://doi.org/10.1016/j.surfcoat.2022.128838（通讯单位：西北工业大学，第一作者：石慧伦博士，通讯作者：付前刚教授、任宣儒副教授）

Graphical Fig. 41. Cross-section BSE micrographs and elemental mappings of the coatings after oxidation: (a) SHS coatings; (b) elemental mapping of (a); (c) CP coatings; (d) elemental mapping of (c).

42. Liu H, Li K, Chen H, et al. Facile growth of oriented SiC nanowires arrays on carbon fiber cloth via CVD[J]. Ceramics International, 2022. Available online 10 August 2022. https://doi.org/10.1016/j.ceramint.2022.08.038（通讯单位：西北工业大学，第一作者：刘慧敏博士，通讯作者：李克智教授、殷学民博士后）

Graphical Fig. 42. Growth mechanism schematic diagram of (a) oriented SiCNWs and (b) randomly distributed SiCNWs.

43. Wu B, Wang P, Ren X, et al. Effect of film-forming regulation of the self-formed compound layer on the oxidation inhibition capacity of HfB2-SiC coating[J]. Ceramics International, 2022. Volume 48, Issue 15, 1 August 2022, Pages 22039-22052. https://doi.org/10.1016/j.ceramint.2022.04.194（通讯单位：中国矿业大学材料科学与物理学院、西安科技大学材料科学与工程学院，第一作者：Binbin Wu博士、王佩佩副教授，通讯作者：任宣儒副教授、Xueqin Kang副教授）

Graphical Fig. 43. Structure factor-inerting factor curves of the film-forming samples oxidized at 1700 °C.

44. Teng L, Shi X H, Wang H H, et al. A new method to improve the laser-ablation resistance of Si-SiC coating on C/C composites: Laser cladding[J]. Journal of the European Ceramic Society, 2022, 42(14): 6425-6434. https://doi.org/10.1016/j.jeurceramsoc.2022.07.028（通讯单位：西北工业大学，第一作者：滕柳博士，通讯作者：李贺军院士、史小红教授）

Graphical Fig. 44. Schematic diagram of ablation mechanism of the (a) PC-Si-SiC sample and (b) LC-Si-SiC sample.

45. Zhang Z, Fang C, Weng Y, et al. Effects of graphene addition on the microstructure and anti-ablation properties of C/C–SiC composites prepared by precursor impregnation and pyrolysis[J]. Ceramics International, 2022. https://doi.org/10.1016/j.ceramint.2022.05.182（通讯单位：中南大学化学与化学工程学院、中南大学轻质高强结构材料国防科技重点实验室，第一作者：Ze Zhang博士，通讯作者：黄启忠教授、Huiping Hu教授）

Graphical Fig. 45. Ablation mechanisms of C/C–SiC composites.

46. Zhang T, Zhang F, Yin X, et al. Important explorations of the sliding tribological performances of micro/nano-structural interfaces: Cross-shaped microconcave and the nanoNb2AlC-Sn[J]. Engineering Failure Analysis, 2022, 142: 106738. https://doi.org/10.1016/j.engfailanal.2022.106738（通讯单位：华北电力大学材料科学与工程学院、南阳理工学院机械与汽车工程学院，第一作者：Taiping Zhang博士，通讯作者：Kang Yang教授、Yongxing Hao教授）

Graphical Fig. 46. Typical morphologies at 20 N of scanning planform (a), 3D and 2D profiles (b, c); statistical height parameters of 2D profile of the 0.5CC-NS-W (d).

47. Shi C, Liu S, Gong Q, et al. Deposition mechanisms and characteristics of nano-modified multimodal Cr3C2–NiCr coatings sprayed by HVOF[J]. Reviews on Advanced Materials Science, 2022, 61(1): 526-538. https://doi.org/10.1515/rams-2022-0042（第一作者：Chenxi Shi博士，通讯作者：Ming Hu教授）

Graphical Fig. 47. Schematic of the formation of the multimodal structure coatings: (a) original particle, (b) molten part of the particle, (c) particle deformation, and (d) cross section of the multimodal coatings.

48. Yang K, Xiao N. Micro/Nanosilver Contribution in Modifying the Lubrication Film to Improve Friction and Wear Behaviors of TiAl-10 wt.% Ag Composite[J]. Advances in Materials Science and Engineering, 2022, 2022. https://doi.org/10.1155/2022/3169938（第一作者：Kang Yang博士，通讯作者：Na Xiao教授）

Graphical Fig. 48. Typical schematic diagram (a) of the TASC/Si3N4 tribo-pair; 3D (b) and (c) 2D profiles of the wear scars of a TASC.

49. Zhang, Yuyu and Sun, Jia and Guo, Lingxiang and Zhang, Xuemeng and Cui, Dingcong and Fu, Qiangang, Ablation Behavior of Zrc Coating Modified by SiC/TaC Nanocomposites Under Oxyacetylene Torch. Available at SSRN: https://ssrn.com/abstract=4068601 or http://dx.doi.org/10.2139/ssrn.4068601（通讯单位：西北工业大学材料学院，第一作者：张育育博士，通讯作者：孙佳副教授、Fu Qiangang教授）

Graphical Fig. 49. Schematic diagram of the formation (a) and ablation mechanisms (b) of prepared coatings.

50. 标题：Strong high-entropy diboride ceramics with oxide impurities at 1800°C

作者：Liu Jie, Yang Qingqing, Zou Ji, Wang Weimin, Wang Xin-Gang, Fu Zhengyi

卷号：SCIENCE CHINA Materials (2022)

链接：https://www.sciengine.com/doi/10.1007/s40843-022-2287-7

DOI：10.1007/s40843-022-2287-7

51. Qiuchen Han, Lei Chang, Zhaoqun Sun, Jiaqi Sun, Zengyan Wei,* , Pingping Wang,*, Ziyang Xiu, Huasong Gou, Pengchao Kang,* and Gaohui Wu. Ablation Mechanism of AlSiB-C/C Composites under an Oxy-Acetylene Torch. Metals 2023, 13, 160. https://doi.org/10.3390/met13010160

52. AE Islam, NP Sepelak, KJ Liddy, R Kahler. 500 °C operation of β-Ga 2 O 3 field-effect transistors. Dec 2022APPL PHYS LETT

53. 张硕, 付前刚, 张佩, 费杰, 李伟. C/C多孔体的高温热处理对C/C-SiC复合材料摩擦磨损行为的影响[J]. 无机材料学报, DOI: 10.15541/jim20220555.

54. ZHANG Shuo, FU Qiangang, ZHANG Pei, FEI Jie, LI Wei. Influence of High Temperature Treatment of C/C Porous Preform on Friction and Wear Behavior of C/C-SiC Composites[J]. Journal of Inorganic Materials, DOI: 10.15541/jim20220555. 链接本文: http://www.jim.org.cn/CN/10.15541/jim20220555

55. Li J, Zhang Y, Zhao Y, et al. A novel (Hf1/3Zr1/3Ti1/3) C medium-entropy carbide coating with excellent long-life ablation resistance applied above 2100° C[J]. Composites Part B: Engineering, 2023, 251: 110467.

56. Jin X, Wu C, Wang H, et al. Synergistic reinforcement and multiscaled design of lightweight heat protection and insulation integrated composite with outstanding high-temperature resistance up to 2500° C[J]. Composites Science and Technology, 2022: 109878.

57. Akhare D, Luo T, Wang J X. Physics-integrated Neural Differentiable (PiNDiff) Model for Composites Manufacturing[J]. 2022.

58. Yang K, Xiao N. Micro/Nanosilver Contribution in Modifying the Lubrication Film to Improve Friction and Wear Behaviors of TiAl-10 wt.% Ag Composite[J]. Advances in Materials Science and Engineering, 2022, 2022.

59. Sun J, Ye D, Zou J, et al. A review on additive manufacturing of ceramic matrix composites[J]. Journal of Materials Science & Technology, 2022.

60. Lu D, Wang H, Su L, et al. Ultrastrong, elastic, and fatigue‐resistant SiC nanowires network[J]. Journal of the American Ceramic Society, 2022, 105(4): 2783-2790.

61. Zhong L, Guo L, Liu N, et al. Ablation behavior of the ZrC coating on C/C composite with the construction of thermal dispersal network[J]. Ceramics International, 2022.

62. Weiyan Wang，Qiangang Fu. Recovery in oxidation behavior of damaged SiC ZrB2/SiC coating of carbon/carbon composites. December 2022，Journal of Materiomics. DOI: 10.1016/j.jmat.2022.11.008. https://doi.org/10.1016/j.jmat.2022.11.008

63. Wang R, Wang N, Zhu S, et al. Study on the mechanism of ultra-high temperature ablation of ZrB2–SiC–TaSi2 coatings by low-pressure plasma spraying on the C/C composites[J]. Ceramics International, 2022.

64. Feng G, Yao X, Yu Y, et al. Response mechanism study of alternate ZrC-10vol.% SiC/ZrC-70vol.% SiC coatings with various sublayer thicknesses for cyclic and long-term thermal exposure[J]. Journal of Materials Science & Technology, 2023, 140: 153-162.

65. Chen Y, Zhang L, Nie H, et al. Synchronously constructing networked Si3N4 nanowires and interconnected graphene inside carbon fiber composites for enhancing mechanical, friction and anti-ablation properties[J]. Journal of Materials Science & Technology, 2023, 142: 167-175.

66. Guo L, Wang Y, Liu B, et al. In-situ phase evolution of multi-component boride to high-entropy ceramic upon ultra-high temperature ablation[J]. Journal of the European Ceramic Society, 2022.

67. Xie X, Tang X, Liao J, et al. Oxidation and ablation behaviours of a SiCnw@ SiC–Si coating fabricated for carbon-fibre-reinforced carbon-matrix composites via thermal evaporation and gaseous silicon infiltration[J]. Ceramics International, 2022.

68. Wang C, Fu Q, Zhao F. Mechanical strengthening and recovery of C/C-Mo joints during thermal cycling[J]. Materials Characterization, 2022, 194: 112461.

69. Qian D, Chen Y, Ren X, et al. Effect of La2O3 content on the oxygen barrier ability of the HfB2‐SiC coating at 1973 K[J]. Journal of the American Ceramic Society, 2022.

70. Tong M, Ding J, Li N, et al. Effect of SiCnws@ BN core shell upon impact-ablation performance of HfC coating on C/C composites[J]. Corrosion Science, 2022, 209: 110707.

71. Shi H, Zhang M, Zhou L, et al. Improved oxidation protective ability of SHS powder-synthesized ZrB2-MoSi2-SiC-Si coating on carbon/carbon composites[J]. Surface and Coatings Technology, 2022, 447: 128838.

72. Zhang T, Zhang F, Yin X, et al. Important explorations of the sliding tribological performances of micro/nano-structural interfaces: Cross-shaped microconcave and the nanoNb2AlC-Sn[J]. Engineering Failure Analysis, 2022, 142: 106738.

73. Deng H, Li J, Zheng J, et al. Improvement in mechanical and ablation properties of carbon/carbon composites with nanofilamentous carbon and CeC2[J]. Corrosion Science, 2022, 207: 110593.

74. Suresh R, Rajendran S. Carbon-based adsorbents for remediation of noxious pollutants from water and wastewater[M]//Sustainable Materials for Sensing and Remediation of Noxious Pollutants. Elsevier, 2022: 177-194.

75. He Q, Li H, Yin X, et al. Microstructure, mechanical and anti-ablation properties of SiCnw/PyC core-shell networks reinforced C/C–ZrC–SiC composites fabricated by a multistep method of chemical liquid-vapor deposition[J]. Ceramics International, 2019, 45(16): 20414-20426.

76. Zheng L, Fang C, Zeng C, et al. Microstructure, mechanical and anti-ablation properties of Mg-modified C/C–ZrC–SiC composites prepared by sol-gel technology[J]. Ceramics International, 2022, 48(23): 34728-34742.

77. Liu H, Li K, Chen H, et al. Facile growth of oriented SiC nanowires arrays on carbon fiber cloth via CVD[J]. Ceramics International, 2022, 48(23): 34543-34549.

附：作者个人主要成果概览：

（1）发表论文：

[1] Pei Zhang, Qiangang Fu*, Chunyu Cheng, Jia Sun, Jiaping Zhang, Min Xu, Xiaofei Zhu. Microstructure evolution of in-situ SiC-HfB2-Si ternary coating and its corrosion behaviors at ultra-high-temperatures. Journal of the European Ceramic Society, 2021, 41(13): 6223-6237. (SCI一区. IF: 5.302，SCI:000683481800002)

[2] Qiangang Fu1*, Pei Zhang1, Lei Zhuang, Lei Zhou, Jiaping Zhang, Jie Wang, Xianghui Hou, Ralf Riedel and Hejun Li*, Micro/nano multiscale reinforcing strategies toward extreme high-temperature applications: Take carbon/carbon composites and their coatings as the examples. Journal of Materials Science & Technology, 2021, 96: 31-68. (SCI一区. IF: 8.067，SCI: 000737296500004，封面论文)

[3] Pei Zhang, Qiangang Fu*, Dou Hu, Chunyu Cheng*, Xiaofei Zhu, Oxidation behavior of SiC-HfB2-Si coating on C/C composites prepared by slurry dipping combined with gaseous Si infiltration, Surface & Coatings Technology, 2020, 385: 125335. (SCI一区. IF: 4.158，SCI: 000526980900011)

[4] Pei Zhang, Qiangang Fu*, Chunyu Cheng*, Xiaofei Zhu, Jinguo Huang, Jiaping Zhang, Wei Li, Comparing oxidation behaviors at 1773 K and 1973 K of HfB2-MoSi2/SiC-Si coating prepared by a combination method of pack cementation, slurry painting and in-situ synthesis. Surface & Coatings Technology, 2020, 403: 126418. (SCI一区. IF: 4.158，SCI: 000590180600073)

[5] Pei Zhang, Qiangang Fu*, Bing Liu, Chunyu Cheng*, Wei Xie, Dou Hu, Jiaping Zhang, Weiyan Wang. Development of SiC-ZrC-based ultra-high-temperature ceramic coatings via composite method of polymer precursor pyrolysis plus gaseous reactive infiltration. Surface and Coatings Technology, 2022, 431: 127996. (SCI一区. IF: 4.158，SCI: 000782662800002)

[6] Pei Zhang, Chunyu Cheng*, Bing Liu, Wei Xie, Xiaofei Zhu, Jiaping Zhang, Qiangang Fu*. Multicomponent (Hf0.25Zr0.25Ti0.25Cr0.25)B2 ceramic modified SiC–Si composite coatings: In-situ synthesis and high-temperature oxidation behavior. Ceramics International, 2022, 48(9): 12608-12624. (SCI一区. IF: 4.527，SCI: 000737296500004)

[7] Pei Zhang, Chunyu Cheng, Min Xu, Bing Liu, Xiaofei Zhu, Qiangang Fu*. High-entropy (Hf0.25Zr0.25Ti0.25Cr0.25)B2 ceramic incorporated SiC-Si composite coating to protect C/C composites against ablation above 2400 K. Ceramics International, 2022, In press. https://doi.org/10.1016/j.ceramint.2022.06.022 (SCI一区. IF: 4.527，SCI: -，EI: )

[8] Jinguo Huang, Lingjun Guo*, Min Xu, Pei Zhang. Effect of pack cementation temperatures on component, microstructure and anti-oxidation performance of Al-modified SiC coatings on C/C composites. Ceramics International, 2020, 46(6): 8293-8298. (SCI一区. IF: 4.527，SCI: 000519661800148)

[9] Wei Xie, Qiangang Fu*, Chunyu Cheng*, Pei Zhang, Ningning Yan. Oxidation behavior of medium-entropy (Y1/3Yb1/3Lu1/3)2O3 modified SiC ceramic at 1700℃: Experimental and theoretical study. Journal of the European Ceramic Society, 2021, 41(12): 5825-5834. (SCI一区. IF: 5.302，SCI: 000661247200006)

[10]  Weiyan Wang, Qiangang Fu*, Jia Sun*, Pei Zhang, Dou Hu. The mechanical and repair behavior of damaged carbon/carbon composites. Ceramics International, 2022, In press. https://doi.org/10.1016/j.ceramint.2022.04.076 (SCI一区. IF: 4.527，SCI: -，EI: )

[11]  Xiaofei Zhu, Yulei Zhang*, Jian Zhang, Tao Li, Wei Xie, Pei Zhang, Honggang Li. A compound glass coating with micro-pores to protect SiC-coated C/C composites against oxidation at 1773 K and 1973 K. Corrosion Science, 2022, 195: 109983. (SCI一区. IF: 7.205，SCI: -，EI: 20214811256105)

[12]  Xiaofei Zhu, Yulei Zhang*, Yangyang Su, Yanqin. Fu, Pei Zhang, SiC-Si coating with micro-pores to protect carbon/carbon composites against oxidation, Journal of the European Ceramic Society, 2021, 41(1): 114-120. (SCI一区. IF: 5.302，SCI: 000582675600010)

[13]  Xiaofei Zhu, Yulei Zhang*, Jian Zhang, Yangyang Su, Ruicong Chen, Pei Zhang. SiC/HfB2-based ceramic/SiC multilayer coating to protect C/C composites against oxidation at medium and high temperatures for long-life service. Corrosion Science, 2022, 201: 110299. (SCI一区. IF: 7.205，SCI: -，EI: 20221511953456)

（2）发明专利：

[14]  付前刚，张佩，李贺军，朱肖飞，周磊，程春玉，魏亚龙，张光朋. 一种具有SiC-HfB2-Si单层复合涂层的碳/碳复合材料的制备方法, 专利申请号：202011341093 .6, 公开 (公告) 号：CN 112409025 A. 国家发明专利.

[15]  付前刚，张佩，李贺军，刘冰，程春玉，孙佳，谢薇，张佳平. 一种成分及微结构可控高熵陶瓷改性涂层的制备及方法, 专利申请号: 202110746078.8, 公开 (公告) 号：CN113321533A. 国家发明专利.

[16]  付前刚, 周磊, 童明德, 徐润洲，张佩. 碳/碳复合材料表面镶嵌SiC-ZrB2-ZrSi2复合抗氧化涂层的制备方法. 专利号：ZL 201410203158.9. 授权日期：2021.02.02. 国家发明专利.

[17]  孙佳，郭凌翔，张育育，刘冰，张佩. 缺陷萤石结构的氧化物高熵陶瓷及其抗烧蚀涂层的制备方法, 专利申请号: 202111188781.8, 公开 (公告) 号：CN113683430A, 国家发明专利.

（3）会议报告（海报）：

[18] 张佩，付前刚*，李贺军，朱肖飞，周磊，魏亚龙. 浆料涂覆结合气相渗硅复合工艺制备碳/碳复合材料用高温抗氧化SiC-HfB2-Si涂层. 第十一届无机非金属材料专题研讨会暨无机非金属材料优秀青年学者论坛，中国西安；2019年8月23日-25日（海报）.

[19] Pei Zhang, Qiangang Fu*, Chunyu Cheng, Xiaofei Zhu, Dou Hu, Jinguo Huang. SiC-HfB2-Si coating prepared by composite technique combining slurry dipping with gaseous Si infiltration to protect carbon/carbon composites against high-temperature oxidation. 第九届高校研究生材料科学与工程论坛，中国武汉；2019年11月8日-10日（口头报告) (优秀报告奖).

[20] 张佩，付前刚*，朱肖飞，黄金果，张佳平. 国内微/纳米相强韧抗氧化碳基复合材料研究现状. 中国复合材料学会空天动力复合材料及应用专业委员会2020年度学术会议，中国六盘水；2020年08月06日-09日(会议论文集，p116-p133).

[21] 张佩，付前刚*，李贺军，张佳平，朱肖飞，周磊，魏亚龙. 浆料涂覆结合气相渗硅复合工艺制备碳/碳复合材料SiC-HfB2-Si抗氧化/烧蚀涂层研究. IFAM 2020新材料国际发展趋势高层论坛，中国西安；2020年10月30日-11月1日 (海报) (优秀海报奖).

[22] Pei Zhang, Qiangang Fu*, Chunyu Cheng, Bing Liu, Wei Xie, Jiangping Zhang, Jia Sun. High-entropy ceramics modified coatings with improved oxidation resistance by reactive infiltration assisted slurry painting method. 12th International Conference on High-Performance Ceramics (CICC-12), Suzhou, China. (海报展讲).

[23] 张佩, 付前刚*, 李贺军*. 面向极端高温环境用微纳多尺度强韧化改性碳/碳复合材料涂层. 2021年首届全国“先进结构工程科学”博士生学术论坛-先进热防护结构及材料技术分论坛, 中国北京（在线会议），军科委先进结构技术专家组、中国力学学会固体力学专业委员会、中国复合材料学会青年工作委员会（主办）、北京理工大学先进结构技术研究员、轻量化多功能复合材料与结构北京市重点试验室（承办）; 2021年11月20日-11月21日（口头报告）.

（4）奖励与荣誉：

[24] “第九届高校材料科学与工程学科研究生论坛”优秀报告奖，武汉理工大学研究生院、材料学院、材料科学与工程国际化示范学院，2019年10月；

[25] 湖南省“高性能材料设计与制备”研究生创新论坛优秀论文奖，湖南省人民政府学位委员会、湖南省教育厅，中南大学研究生院、材料科学与工程学院，2020年10月；

[26] “IFAM2020新材料国际发展趋势高层论坛”优秀Poster奖，中国工程院化工、冶金与材料工程学部，中国材料研究学会、材料学术联盟、国家新材料产业发展战略咨询委员会，2020年10月；

[27] “第十一届高校材料科学与工程学科研究生论坛”优秀墙报奖，武汉理工大学研究生院、材料学院、材料科学与工程国际化示范学院，2021年11月。

附：（1）作者个人页：

（2）所在团队近年代表性学术专著

综述文章的完整参考文献

(The work of the authors were highlighted in yellow)

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